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Properties of substance:

4-methylbiphenyl

Group of substances:

organic

Empirical formula (Hill's system for organic substances):

C13H12

Structural formula as text:

CH3C6H4C6H5

Molar/atomic mass: 168.2344

Melting point (°C):

48.1

Boiling point (°C):

273

Solubility (g/100 g of solvent):

carbon tetrachloride: sparingly soluble [Ref.]
diethyl ether: soluble [Ref.]
ethanol: soluble [Ref.]
water: insoluble [Ref.]

Reactions of synthesis:

  1. Yeild 21%. [Ref.1aster]
    CH3C6H4NH2 + NaNO2 + 2HCl → CH3C6H4N2Cl + NaCl + 2H2O
    CH3C6H4N2Cl + NaOH + C6H6 → CH3C6H4C6H5 + NaCl + N2 + H2O

Retention indices for gas chromatography:

1497,3 (phase - DB-5, temperature-programmed conditions, 6 K/min)

References:

  1. CRC Handbook of Chemistry and Physics. - 95ed. - CRC Press, 2014. - pp. 3-360

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru