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Properties of substance:
carbon tetrabromide
Synonyms:
tetrabromomethane
Group of substances:
organic
Physical appearance:
colorless monoclinic crystals
Empirical formula (Hill's system for organic substances):
CBr
4
Structural formula as text:
CBr4
Molar/atomic mass: 331.65
Melting point (°C):
92.3
Boiling point (°C):
189.5
Decomposition temperature (°C):
189.5
CAS №: 558-13-4
Solubility (g/100 g of solvent):
bromine liquid
: soluble [
Ref.
]
carbon disulphide
: very soluble [
Ref.
]
chloroform
: soluble [
Ref.
]
diethyl ether
: soluble [
Ref.
]
ethanol
: soluble [
Ref.
]
water
: 0.024 (30°C) [
Ref.
]
Density:
2.9609 (100°C, d
4
)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
29.4 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
47.7 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
212.5 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
144.3 (s)
Molar enthalpy (heat) of fusion Δ
fus
H (kJ/mol):
4
Enthalpy (heat) of vaporization Δ
vap
H (kJ/mol):
38
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
83.9 (g)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
67 (g)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
358.1 (g)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
91.2 (g)
References:
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 3-468, 5-19
Seidell A. Solubilities of organic compounds. - 3ed., vol.2. - New York: D. Van Nostrand Company, 1941. - pp. 1
Yalkowsky S.H., Yan H. Handbook of aqueous solubility data. - CRC Press, 2003. - pp. 16
Ефимов А.И. и др. Свойства неорганических соединений. Справочник. - Л.: Химия, 1983. - pp. 204-205 [Russian]
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 530 [Russian]
Реми Г. Курс неорганической химии. - Т.1. - М., 1963. - pp. 480 [Russian]
Свойства органических соединений: Справочник. - Под ред. Потехина А.А. - Л.: Химия, 1984. - pp. 232-233 [Russian]
Справочник по растворимости. - Т.1, Кн.2. - М.-Л.: ИАН СССР, 1962. - pp. 1042-1043 [Russian]
Справочник химика. - 2 изд., Т. 2. - Л.-М.: Химия, 1964. - pp. 1018-1019 [Russian]
Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 570 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru