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Properties of substance:
tetraamminecopper(II) sulfate monohydrate
Group of substances:
inorganic
Physical appearance:
blue rhombic crystals
Empirical formula (Hill's system for organic substances):
H
1
4
CuN
4
O
5
S
Structural formula as text:
[Cu(NH3)4]SO4 * H2O
Molar/atomic mass: 245.74
Decomposition temperature (°C):
200
Solubility (g/100 g of solvent):
ethanol
: insoluble [
Ref.
]
water
: 18.5 (21.5°C) [
Ref.
]
Density:
1.81 (20°C, g/cm
3
)
Reactions:
[
Ref.1
]
[Cu(NH
3
)
4
]SO
4
* H
2
O + 3H
2
S → CuS + (NH
4
)
2
SO
4
+ 2NH
4
HS + H
2
O
Electrode potential:
Cu(NH
3
)
4
2+
+ 2e
-
→ Cu + 4NH
3
, E = -0.05 V (water, 25°C)
References:
Galwey A.K., Brown M.E. Thermal Decomposition of Ionic Solids. - Elsevier, 1999. - pp. 509
Гороновский И.Т., Назаренко Ю.П., Некряч Е.Ф. Краткий справочник по химии. - 5 изд. - Киев: Наукова думка, 1987. - pp. 264-265 [Russian]
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 126-127 [Russian]
Энциклопедия для детей. - Т.17: Химия. - М.: Аванта+, 2004. - pp. 166 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru