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Properties of substance:
2,6-diisopropylphenol
Synonyms:
diprivan
propofol
Group of substances:
organic
Physical appearance:
colorless liquid
Empirical formula (Hill's system for organic substances):
C
1
2
H
1
8
O
Structural formula as text:
((CH3)2CH)2C6H3OH
Molar/atomic mass: 178.2707
Melting point (°C):
19
Boiling point (°C):
256
CAS ¹: 2078-54-8
Solubility (g/100 g of solvent):
2-propanol
: sparingly soluble [
Ref.
]
cyclohexane
: sparingly soluble [
Ref.
]
ethanol
: very soluble [
Ref.
]
methanol
: very soluble [
Ref.
]
water
: 0.016 [
Ref.
]
Density:
0.955 (20°C, g/cm
3
)
Reactions of synthesis:
Yeild 65%. [
Ref.1
]
C
6
H
5
OH + 2CH
3
CH=CH
2
→ ((CH
3
)
2
CH)
2
C
6
H
3
OH
Yeild 61%. [
Ref.1
]
C
6
H
5
OH + 2CH
3
CH=CH
2
→ ((CH
3
)
2
CH)
2
C
6
H
3
OH
Yeild 60%. [
Ref.1
,
Ref.2
,
Ref.3
]
HO((CH
3
)
2
CH)
2
C
6
H
2
COOH + 2NaOH → ((CH
3
)
2
CH)
2
C
6
H
3
OH + Na
2
CO
3
+ H
2
O
Refractive index (n
D
):
1.514 (20°C)
Vapour pressure (Torr):
30 (136°C)
LD
50
(mg/kg):
42 (rats, intravenous)
50 (mice, intravenous)
170 (mice, intraperitoneal)
References:
Messina L.C., Silva de Espindola C., Omori A.T. Direct One-Pot Synthesis of Propofol from Paracetamol Tablets / ACS Sustainable Chemistry & Engineering. - 2023. - Vol. 11, No. 5. - pp. 1638-1642 [DOI:
10.1021/acssuschemeng.2c07483
]
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 3-442
CRC Handbook of Chemistry and Physics. - 95ed. - CRC Press, 2014. - pp. 3-468
Drugs. - 1987. - Vol. 34, No. 1. - pp. 115-119
Elks J., Ganellin C.R. Dictionary of Drugs: Chemical Data, Structures and Bibliographies. - Springer, 1990. - pp. 425
Lewis R.J. Sax's Dangerous Properties of Industrial Materials. - 12ed., Vol. 1-5. - Wiley, 2012. - pp. 1648
Organic Process Research and Development. - 2014. - Vol. 18, No. 1. - pp. 152-156 [DOI:
10.1021/op400300t
]
The Merck Index. - 15th ed. - Royal Society of Chemistry, 2013. - pp. 1451-1452
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru